Petalite




Silicate mineral, used in ceramic glazing














































































































Petalite

Petalite.jpg
Petalite from Minas Gerais State, Brazil (size: 3x4 cm)

General
Category Phyllosilicate

Formula
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(repeating unit)
LiAlSi4O10
Strunz classification 9.EF.05
Crystal system Monoclinic
Crystal class Prismatic (2/m)
(same H-M symbol)
Space group P2/a
Unit cell a = 11.737 Å,
b = 5.171 Å,
c = 7.63 Å;
β = 112.54°; Z = 2
Identification
Color Colorless, grey, yellow, pink, to white
Crystal habit Tabular prismatic crystals and columnar masses
Twinning Common on {001}, lamellar
Cleavage Perfect on {001}, poor on {201} with 38.5° angle between the two
Fracture Subconchoidal
Tenacity Brittle

Mohs scale
hardness
6 – 6.5
Luster Vitreous, pearly on cleavages
Streak Colorless
Diaphaneity Transparent to translucent
Specific gravity 2.4
Optical properties Biaxial (+)
Refractive index nα=1.504, nβ=1.510, nγ=1.516
Birefringence δ = 0.012
2V angle 82 – 84° measured
Melting point 1350 °C[1]
Fusibility 5
Solubility Insoluble
References
[2][3][4][5]

Petalite, also known as castorite, is a lithium aluminium phyllosilicate mineral LiAlSi4O10, crystallizing in the monoclinic system. Petalite is a member of the feldspathoid group. It occurs as colorless, grey, yellow, yellow grey, to white tabular crystals and columnar masses. Occurs in lithium-bearing pegmatites with spodumene, lepidolite, and tourmaline. Petalite is an important ore of lithium, and is converted to spodumene and quartz by heating to ~500 °C and under 3 kbar of pressure in the presence of a dense hydrous alkali borosilicate fluid with a minor carbonate component.[6] Petalite (and secondary spodumen formed from it) is lower in iron than primary spodumen making it a more useful source of lithium in e.g. the production of glass. The colorless varieties are often used as gemstones.



Discovery and occurrence




Petalite from Paprok, Nuristan Province, Afghanistan (size: 7.3 x 2.9 x 2.4 cm)


Discovered in 1800, by Brazilian naturalist and statesman Jose Bonifacio de Andrada e Silva. Type locality: Utö Island, Haninge, Stockholm, Sweden. The name is derived from the Greek word petalon, which means leaf (perfect cleavage).[4][7][8]


Economic deposits of petalite are found near Kalgoorlie, Western Australia; Aracuai, Minas Gerais, Brazil; Karibib, Namibia; Manitoba, Canada; and Bikita, Zimbabwe.


The first important economic application for petalite was as a raw material for the glass-ceramic cooking ware CorningWare.[citation needed] It has been used as a raw material for ceramic glazes.



References





  1. ^ "Petalite". Digital Fire. Retrieved 23 October 2011..mw-parser-output cite.citation{font-style:inherit}.mw-parser-output .citation q{quotes:"""""""'""'"}.mw-parser-output .citation .cs1-lock-free a{background:url("//upload.wikimedia.org/wikipedia/commons/thumb/6/65/Lock-green.svg/9px-Lock-green.svg.png")no-repeat;background-position:right .1em center}.mw-parser-output .citation .cs1-lock-limited a,.mw-parser-output .citation .cs1-lock-registration a{background:url("//upload.wikimedia.org/wikipedia/commons/thumb/d/d6/Lock-gray-alt-2.svg/9px-Lock-gray-alt-2.svg.png")no-repeat;background-position:right .1em center}.mw-parser-output .citation .cs1-lock-subscription a{background:url("//upload.wikimedia.org/wikipedia/commons/thumb/a/aa/Lock-red-alt-2.svg/9px-Lock-red-alt-2.svg.png")no-repeat;background-position:right .1em center}.mw-parser-output .cs1-subscription,.mw-parser-output .cs1-registration{color:#555}.mw-parser-output .cs1-subscription span,.mw-parser-output .cs1-registration span{border-bottom:1px dotted;cursor:help}.mw-parser-output .cs1-ws-icon a{background:url("//upload.wikimedia.org/wikipedia/commons/thumb/4/4c/Wikisource-logo.svg/12px-Wikisource-logo.svg.png")no-repeat;background-position:right .1em center}.mw-parser-output code.cs1-code{color:inherit;background:inherit;border:inherit;padding:inherit}.mw-parser-output .cs1-hidden-error{display:none;font-size:100%}.mw-parser-output .cs1-visible-error{font-size:100%}.mw-parser-output .cs1-maint{display:none;color:#33aa33;margin-left:0.3em}.mw-parser-output .cs1-subscription,.mw-parser-output .cs1-registration,.mw-parser-output .cs1-format{font-size:95%}.mw-parser-output .cs1-kern-left,.mw-parser-output .cs1-kern-wl-left{padding-left:0.2em}.mw-parser-output .cs1-kern-right,.mw-parser-output .cs1-kern-wl-right{padding-right:0.2em}


  2. ^ Handbook of Mineralogy


  3. ^ Webmineral


  4. ^ ab Mindat


  5. ^ *Hurlbut, Cornelius S. and Klein, Cornelis, 1985, Manual of Mineralogy, Wiley, 20th ed., pp. 459–460
    ISBN 0-471-80580-7



  6. ^ Deer, W. A. (2004). Framework silicates: silica minerals, feldspathoids and the zeolites (2. ed.). London: Geological Soc. p. 296. ISBN 1-86239-144-0.


  7. ^ D'Andraba (1800). "Des caractères et des propriétés de plusieurs nouveaux minérauxde Suède et de Norwège , avec quelques observations chimiques faites sur ces substances". Journal de chimie et de physique. 51: 239.


  8. ^ Sowerby, James (1811). Exotic mineralogy: Or, Coloured figures of foreign minerals: As a supplement to British mineralogy.




External links




  • Media related to Petalite at Wikimedia Commons


  • Wikisource "Petalite" . Encyclopædia Britannica. 21 (11th ed.). 1911.









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